By checking their docs example
app.layout = html.Div([
dcc.Dropdown(['New York City', 'Montréal', 'San Francisco'], 'Montréal')
])
Seems you just need to provide a tuple with 2 items, a list and a default value.
Maybe give this a try?
states = ['AL','AR','AZ','CA'] # ...
dcc.Dropdown(id='select_st',
options=(states, states[-1]),
value='FL',
style={
'width':'80%',
'padding':'3px',
'font-size':'20px',
'text-align':'left'})