Not sure if this is the best way but it works by using the InsertHeader transformer and setting the header name prefixed with "CamelHeader." so that it gets picked up by the connector.
Example yaml configuration:
class: org.apache.camel.kafkaconnector.https.CamelHttpsSinkConnector
config:
transforms: addContentTypeHeader
transforms.addAuthHeader.type: org.apache.kafka.connect.transforms.InsertHeader
transforms.addAuthHeader.header: CamelHeader.Content-Type
transforms.addAuthHeader.value.literal: application/json