The configuration of the multi-monitor comprises 2 steps :
Enable the multi-monitor configuration, which is described in VMware online documentation.
Use the second monitor with the VMware. This step appears to be a little hidden.
To enable the multi-monitor configuration :
Stop the virtual machine if it is already running
Launch Virtual Machine settings -> Hardware -> Display.
Set the number of monitors here and the maximum resolution of any of the monitors
To use the second monitor :