Can you remove the X-HTTP-Method key and MERGE value from the Headers? This suggests that you want to update an existing item. If I understand correctly you want to create a new list item?
Below is an example of the REST API documentation, if that helps?
In case of an update you would also want to refer to the id of the item in your URI
POST https://{site_url}/_api/web/lists/GetByTitle('Test')/items({item_id})